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The combustion behavior in a modem 4-valve engine using a broad range of methanol/gasoline fuel mixtures was studied. The initial flame development was examined by using a spark plug fiber optics probe. Approximately, the kernel expansion speed, Sg, is relatively unchanged from M0 to M40; jumps by ∼30% from M40 to M60; and then remains roughly constant from M60 to M100. Statistics of the IMEP indicate that at a lean idle condition the combustion rate and robustness correlate with Sg: a higher value of Sg gives better combustion. Thus M60-M100 fuels give better idle combustion behavior than the M0-M40 fuels.

The chemistry of unburned hydrocarbon oxidation in SI engine exhaust was modeled as a function of temperature and concentration of unburned gas for lean and rich mixtures. Detailed chemical kinetic mechanisms were used to model isothermal reactions of unburned fuel/air mixture in an environment of burned gases at atmospheric pressure. Simulations were performed using five pure fuels (methane, ethane, propane, n-butane and toluene) for which chemical kinetic mechanisms and steady state hydrocarbon (HC) emissions data were available. A correlation is seen between reaction rates and HC emissions for different fuels. Calculated relative amounts of intermediate oxidation products are shown to be consistent with experimental measurements.

Currently, states that are out of compliance with the National Ambient Air Quality Standards must, according to the Clean Air Act Amendments of 1990 (CAAA), develop and implement control strategies that demonstrate specific degrees of reduction in emissions-with the degree of reduction depending upon the severity of the problem. One tool that has been developed to aid regulators in both deciding an appropriate course of action and to demonstrate the desired reductions in mobile emissions is EPA's Mobile 5a emission estimation model. In our study, Mobile 5a has been used to examine the effects of regulatory strategies, as applied to the Northeast United States, on vehicle emissions under worst-case ozone-forming conditions.

The engine-out (EO) total and speciated hydrocarbon emissions data from the Auto-Oil Program Phase II Heavy Hydrocarbon Study had been analyzed. The methodology was to first investigate the stabilized EO emissions (Bag 2) of a specific vehicle (Vehicle 04B, a 1989 Model Year Ford Taurus); then the vehicle-to-vehicle differences in Bag2 emissions were considered. Finally, the differences in the Bag2 and the starting/warm-up EO emissions (Bag1) were examined. The speciated emissions may be interpreted as a “feed-through” part due to the unreacted fuel species, and an “offset” part due to the decomposition products. The significant non-fuel emitted species were methane and the olefins. The HC emissions for vehicles with different total emissions were similar in species composition. For both the total and speciated emissions, there was no substantial difference between the Bag1 and Bag2 values for Vehicle 04B.

A technique has been developed to measure the desorption and subsequent oxidation of fuel in the oil layer by spiking the oil with liquid fuel and firing the engine on gaseous fuel or motoring with air. Experiments suggest that fuel desorption is not diffusion limited above 50 °C and indicated that approximately two to four percent of the cylinder oil layer is fresh oil from the sump. The increase in hydrocarbon emissions is of the order of 100 ppmC1 per 1% liquid fuel introduced into the fresh oil in a methane fired engine at mid-speed and light load conditions. Calculations indicate that fuel desorbing from oil is much more likely to produce hydrocarbon emissions than fuel emerging from crevices.

The extent of oxidation of hydrocarbons desorbing from the oil layer has been measured directly in a hydrogen-fueled, spark-ignited engine in which the lubricant oil was doped with a single component hydrocarbon. The amount of hydrocarbon desorbed and oxidized could be measured simultaneously as the dopant was only source of carbon-containing species. The fraction oxidized was strongly dependent on engine load, hydrogen fuel-air ratio and dopant chemical reactivity, but only modestly dependent on spark timing and nitrogen dilution levels below 20 percent. Fast FID measurements at the cylinder exit showed that the surviving hydrocarbons emerge late in the exhaust stroke.

A sampling system was developed to measure the evolution of the speciated hydrocarbon emissions from a single-cylinder SI engine in a simulated starting and warm-up procedure. A sequence of exhaust samples was drawn and stored for gas chromatograph analysis. The individual sampling aperture was set at 0.13 s which corresponds to ∼ 1 cycle at 900 rpm. The positions of the apertures (in time) were controlled by a computer and were spaced appropriately to capture the warm-up process. The time resolution was of the order of 1 to 2 cycles (at 900 rpm). Results for four different fuels are reported: n-pentane/iso-octane mixture at volume ratio of 20/80 to study the effect of a light fuel component in the mixture; n-decane/iso-octane mixture at 10/90 to study the effect of a heavy fuel component in the mixture; m-xylene and iso-octane at 25/75 to study the effect of an aromatics in the mixture; and a calibration gasoline.

A method to collect and speciate the components of gasoline absorbed in the lubricant oil using gas chromatography has been developed. Samples were collected continuously from the piston skirt, baffle and sump in a Saturn engine. A long (18 hours) test was performed to determine the build up of hydrocarbons in the sump, and a shorter (25 min) test was performed to determine the build up of hydrocarbons in the piston skirt and baffle during engine warm-up. The first experiment showed that the total hydrocarbon concentration in the sump oil reached a steady state of about 1.35% mass fraction after 11 hours of engine operation. The relative concentration of individual fuel hydrocarbon species absorbed in the oil increases exponentially with boiling point. Most of the identified species in the oil consist of the heavy end aromatics. Similar compositions but lower concentrations were found for samples collected from the piston skirt during engine warm-up.

The fuel effects on throttle transients in PFI spark ignition engines were assessed through experiments with simultaneous step change of the throttle position from part load to WOT and increment of the injected fuel amount. The test matrix consisted of various gasoline/methanol blends from pure gasoline to pure methanol, coolant temperatures at 40C (for cold engine condition) and 80C (for warm engine), and different levels of fuel enrichment at the WOT condition. The x-τ model was used to interpret the engine GIMEP response in the transient. Using the model, a procedure was developed to calculate the parameters of the transient from the data. These parameters were systematically regressed against the fuel distillation points, the increment in injected fuel mass in the transient, and the enthalpy required to evaporate the fuel increment as the explanatory variables.

The knocking characteristics of several fuels are studied using a single cylinder test engine with variations in key engine operating parameters. Compression ratio, spark advance, fuel equivalence ratio, exhaust gas recirculation, engine speed, charge inlet pressure and charge inlet temperature were varied to yield a range of engine cylinder pressure-temperature histories as the base for this study. The fuels studied include three reference fuels containing isooctane and heptane with isooctane volume percents of 80, 90 and 100. Two wide boiling range gasolines were also studied. A number of empirical relationships for autoignition times of isooctane and heptane blends are employed in conjunction with the experimentally obtained pressure-temperature histories to predict onset of knock. The accuracies of the predictions with respect to the experimentally determined knock points are discussed.

THIS paper reports the latest investigation of the relative merits of loop scavenging versus through scavenging. The authors hope that the conditions of the work permitted an objective evaluation of the two types of engines. The results of the study may be summarized as follows: 1. With symmetrical timing, neither cylinder shows significant advantage in trapping efficiency. 2. With symmetrical timing, the best ratio of exhaust-port to inlet-port effective area seems to be about 0.6. 3. Unsymmetrical timing is an effective method of improving trapping efficiency. 4. The value of net indicated fuel economy shows no significant difference between the two cylinders. The authors point out that because the areas were equal it is unlikely that the optimum port design of each type was used in comparing the cylinders. If optimum porting had been used, the two types might have shown more difference.

Three fuels with cetane numbers of 45, 36 and 29 have been run at four load levels at each of three speeds in a Detroit: Diesel 3–71 engine with standard injectors. Measurements of temperatures, pressures, Load, fuel flow, cylinder pressure in one cylinder, strain gauge measurements from the rocker arm operating one injector and exhaust emissions were all recorded. Comparisons show little change in operation except for increases in ignition delay and rate of cylinder pressure rise with the low cetane fuels. It was concluded, on the basis of these short runs, that the intermediate fuel probably would not cause major difficulties but the lowest cetane fuel could possibly present problems with noise and engine durability.

The present day measure of the ignition quality of a diesel fuel is the cetane number. Cetane number determination is carried out using a special single cylinder engine with reproducible operating conditions and variable compression ratio. The importance of the carbon skeletal structure of the fuel on the ignition quality is qualitatively well known, but the practice of defining the ignition quality of diesel fuels by a term, whose physical and/or chemical meaning is not well understood, has not been abandoned yet. The correlations that have been proposed recently, which relate the total fuel aromaticity or mid-boiling point, hydrogen content and density to the cetane number, suffer from the lack of representation of the fuel's compositional structure, and of well defined relationship, if any, between boiling point, hydrogen content, density and ignition quality.

THE autoignition characteristics of several fuels under various conditions of mixture strength, compression ratio, and temperature have been studied by means of a rapid-compression machine. The behaviors of a knock inhibitor, tetraethyl lead, and a knock inducer, ethyl nitrite, have also been studied. Simultaneous records of pressure, volume, and the inflammation have been obtained. These records show the diverse aspects of the autoignition phenomenon and indicate, among other things, according to the authors, that a comparison of the detonating tendencies of fuels must include not only a consideration of the length of the delay period but also an evaluation of the rate of pressure rise during autoignition. Physical interpretations of the data are presented but chemical interpretations have been avoided. The work was exploratory in nature. The authors hope that the results will stimulate activity in this important branch of combustion research.

Six experimental fuels representative of Canadian future fuel options were tested against a reference fuel in a Bombardier 12 cylinder, 4 stroke, 3000 hp, medium speed diesel. The reference fuel was a straight run ASTM #2-D. The first test fuel blend consisted of heavy atmospheric gas oil that extended the distillation range (higher end point) of the other blend component ASTM #2-D. The second fuel was a blend of a distillate cut from a mixture of conventional and tar sands crude with hydrogen treated cracked stock. This provided a fuel with substantial levels of aromatic and cracked components. The third fuel was gas oil side stream: a low cetane number, high aromatics level tar sands distillate. The fourth fuel was an equal portion blend of tar sands crude components, gas oil side-stream and heavy unifined gas oil. The fifth fuel was a blend of ASTM #2-D heating oil and a substantial portion of stabilized cracked stock.

A critical evaluation of the current ASTM method of rating diesel fuels, and of the available non-engine techniques for the estimation of cetane nunbers of diesel fuels is presented. The relationship between ignition quality and fuel composition is reviewed and it is shown that each member of an homologous series of hydrocarbons does not have the same ignition characteristics as the other members of the series. It is emphasized that the belief that paraffins have relatively high cetane ratings as compared to aromatics and cycloparaffins is not always correct. The basic flaw in the cetane index correlations, which use the easily measurable physical properties of the fuels as independent parameters, is explained. A fuel data base has been used to compare the different correlations.

Four experimental diesel fuels with cetane numbers (CN) of 40, 37, 35 and 27 have been tested in a Detroit Diesel Allison 3-71 engine using the standard N65 injectors. The 35 CN fuel was a blend of distillates from conventional and tar sands crude with hydrogen treated cat-cracked stock. This provided a fuel typical of the 1990's and beyond, with substantial levels of aromatic and cracked components. The 27 CN fuel was a blend of the same components as the 35 CN fuel only with a larger portion of the hydrogen treated cat-cracked component. The 40 CN fuel was identical to the 35 CN fuel with a .2% DII-3 Diesel Ignition Improver. The 37 CN fuel was a blend of Canadian winter diesel fuel oil and 24% Light Cycle Oil (LCO), The four experimental fuels and one reference fuel were tested at four load levels at each of three engine speeds. The performance and combustion characteristics were compared with the physical and chemical fuel properties.

Two Canadian tar sands derived experimental diesel fuels with cetane numbers of 26 and 36 and a reference fuel with a cetane number of 47 were tested in a Deutz (F1L511D), single cylinder, A stroke, naturally aspirated research engine. The fuels were tested at intake and cooling air temperatures of 30 and 0°C. The 36 cetane number fuel was tested with advanced, rated and retarded injection timings. Poor engine speed stability at light loads and excessive rates of combustion pressure rise were experienced with the lowest cetane number fuel. Detailed performance/combustion behavior is presented and a correlation with fuel structural composition is made. The analytical techniques used to characterize the fuels included liquid chromatography, gas chromatography mass spectrometry (GC-MS) and proton nuclear magnetic resonance spectrometry (PNMR).

Spark-ignition engine knock was characterized in terms of when during the engine cycle and combustion process knock occurred and its magnitude or intensity. Cylinder pressure data from a large number of successive individual cycles were generated from a single-cylinder engine of hemispherical chamber design over a range of operating conditions where knock occurred in some or all of these cycles. Mean values and distributions of following parameters were quantified: knock occurrence crank angle, knock intensity, combustion rate and the end-gas thermodynamic state. These parameters were determined from the cylinder pressure data on an individual cycle basis using a mass-burn-rate analysis. The effects of engine operating variables on these parameters were studied, and correlations between these parameters were examined.

The use of hydrogen as a fuel supplement for lean-burn engines at higher compression ratios has been studied extensively in recent years, with good promise of performance and efficiency gains. With the advances in reformer technology, the use of a gaseous fuel stock, comprising of substantially higher fractions of hydrogen and other flammable reformate species, could provide additional improvements. This paper presents the performance and emission characteristics of a gas mixture of equal volumes of hydrogen, CO, and methane. It has recently been reported that this gas mixture can be produced by reforming of ethanol at comparatively low temperature, around 300C. Experiments were performed on a 1.8-liter passenger-car Nissan engine modified for single-cylinder operation. Special pistons were made so that compression ratios ranging from CR= 9.5 to 17 could be used. The lean limit was extended beyond twice stoichiometric (up to lambda=2.2).